Carbon−Oxygen and Carbon−Hydrogen Bond Cleavage Reactions of ortho-Substituted Phenols by Ruthenium(II) Complexes

Carbon−Oxygen and Carbon−Hydrogen Bond Cleavage Reactions of ortho-Substituted Phenols by Ruthenium(II) Complexes
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DOI：
10.1021/om061183m
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发表时间：
2007-03
期刊：
Organometallics
影响因子：
2.8
通讯作者：
M. Hirano;Hiromi Sato;Naoki Kurata;Nobuyuki Komine;S. Komiya
M. Hirano;Hiromi Sato;Naoki Kurata;Nobuyuki Komine;S. Komiya
中科院分区：
化学2区
文献类型：
--
作者：
M. Hirano;Hiromi Sato;Naoki Kurata;Nobuyuki Komine;S. Komiya

文献摘要

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Ru（η_4 - 1，5-COD）（η_6 - 1，3，5-COT）（1）（COD =环辛烯（C_8H_（1 -2）与一元取代苯酚HOC_6 H_4（R_1 -2）（R_1 = OMe，CHO，CO_2Me）在PMe_3存在下反应，生成相应的oxaruthena.
Treatment of Ru(η4-1,5-COD)(η6-1,3,5-COT) (1) (COD = cyclooctadiene (C8H12)) with a monosubstituted phenol HOC6H4(R1-2) (R1 = OMe, CHO, CO2Me) in the presence of PMe3 gives corresponding oxaruthena...