Formation and Crystal Structure of Two-Component Host System Having Helical Chirality and Comprising 9,10-Dihydro-9,10-ethanoanthracene-11,12-diamine and 1,1′-Binaphthyl-2,2′-dicarboxylic Acid
Formation and Crystal Structure of Two-Component Host System Having Helical Chirality and Comprising 9,10-Dihydro-9,10-ethanoanthracene-11,12-diamine and 1,1′-Binaphthyl-2,2′-dicarboxylic Acid
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DOI：
10.1021/cg800911x
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发表时间：
2009-01
影响因子：
3.8
通讯作者：
Y. Imai;Katuzo Murata;Kensaku Kamon;Takafumi Kinuta;Tomohiro Sato;R. Kuroda;Y. Matsubara
中科院分区：
文献类型：
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作者：
Y. Imai;Katuzo Murata;Kensaku Kamon;Takafumi Kinuta;Tomohiro Sato;R. Kuroda;Y. Matsubara
将具有中心手性的(11R,12R)-9,10-二氢-9,10-乙基蒽- 1,12-二胺和具有轴向手性的(S)-1,1′-二萘-2,2′-二羧酸结合，成功地形成了具有多个手性点（中心、轴和螺旋）的双组分超分子宿主体系，其中可以包含一个正烷基醇分子。该宿主体系的螺旋手性是由固态组分分子的中心手性和轴向手性诱导的。
A two-component supramolecular host system having multiple chiral points (central, axial, and helical), which can include an n-alkyl alcohol molecule, was successfully formed by combining (11R,12R)-9,10-dihydro-9,10-ethanoanthracene-11,12-diamine with central chirality and (S)-1,1′-binaphthyl-2,2′-dicarboxylic acid with axial chirality. The helical chirality of this host system was induced by the central and axial chiralities of the component molecules in solid state.