Mn(III)-Catalyzed Aerobic Oxidation of 3-Alkyl-4-hydroxy-1H-pyrrol-2(5H)-ones in the Presence of 1,1-Diarylethenes. Synthesis of Stable 8-Aza-1-hydroxy-2,3-dioxabicyclo[4.3.0]nonan-7-one Framework
Mn(III)-Catalyzed Aerobic Oxidation of 3-Alkyl-4-hydroxy-1H-pyrrol-2(5H)-ones in the Presence of 1,1-Diarylethenes. Synthesis of Stable 8-Aza-1-hydroxy-2,3-dioxabicyclo[4.3.0]nonan-7-one Framework
复制标题
1,1-二芳基乙烯存在下 Mn(III) 催化的 3-烷基-4-羟基-1H-吡咯-2(5H)-酮的有氧氧化。
DOI：
10.1002/jhet.1840
复制
发表时间：
2014
期刊：
影响因子：
--
通讯作者：
Md. Aminul Haque and Hiroshi Nishino*
中科院分区：
文献类型：
--
作者：
Nobutaka Kikue;Tetsuya Takahashi;and Hiroshi Nishino*;Risa Matsumoto and Hiroshi Nishino*;Nguyen Van Ha* and Hiroshi Nishino;Md. Aminul Haque and Hiroshi Nishino*
制备了22个3 -烷基- 4 -羟基- 1H -吡咯- 2(5H) -酮，并在1,1 -二乙烯的存在下进行了Mn（III）催化的好氧氧化，得到了非常稳定的晶体6 -烷基- 8 - aza - 4,4 -二芳基- 1 -羟基- 2,3 -二恶比环[4.3.0]nonan - 7 -酮。
Twenty‐two 3‐alkyl‐4‐hydroxy‐1H‐pyrrol‐2(5H)‐ones were prepared and underwent Mn(III)‐catalyzed aerobic oxidation in the presence of 1,1‐diarylethenes to produce very stable crystalline 6‐alkyl‐8‐aza‐4,4‐diaryl‐1‐hydroxy‐2,3‐dioxabicyclo[4.3.0]nonan‐7‐ones in high yields.