Liquid Surface Tension near the Triple Point

Liquid Surface Tension near the Triple Point
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三相点附近的液体表面张力

DOI:
10.1063/1.1674388
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发表时间:
1970
影响因子:
4.4
通讯作者:
B. Widom
B. Widom
中科院分区:
化学2区
文献类型:
--
作者:
P. A. Egelstaff;B. Widom

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结果表明,液体在其三相点附近的等温压缩率ξ与表面张力Σ的乘积可以预期为液体的基本长度特性。从30种液体(包括液态金属)的实验数据可以观察到,当ξ和Σ分别以150的倍数变化时,乘积ξΣ变化的倍数小于3,并且总是等于十分之一埃单位。
It is shown that the product of the isothermal compressibility ξ and surface tension Σ of a liquid near its triple point may be expected to be a fundamental length characteristic of the liquid. From experimental data on 30 liquids (including liquid metals) it is observed that while ξ and Σ separately vary by a factor of 150, the product ξΣ varies by a factor of less than 3 and is equal always to a few tenths of an angstrom unit.