Homogeneous photocatalytic production of hydrogen from water by a bioinspired [Fe(2)S(2)] catalyst with high turnover numbers.
Homogeneous photocatalytic production of hydrogen from water by a bioinspired [Fe(2)S(2)] catalyst with high turnover numbers.
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DOI：
10.1039/b923159p
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发表时间：
2010-01
影响因子：
4
通讯作者：
Pan Zhang;Mei Wang;Y. Na;Xueqian Li;Yi Jiang;Licheng Sun
中科院分区：
文献类型：
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作者：
Pan Zhang;Mei Wang;Y. Na;Xueqian Li;Yi Jiang;Licheng Sun
由环金属化铱 (iii) 光敏剂、仿生二铁络合物和丙酮水溶液中的 TEA 组成的三组分均相催化剂体系被证明对光诱导 H(2) 生产具有催化活性，在 8 小时的照射下，转换次数高达 660 次。
A three-component homogeneous catalyst system, composed of a cyclometalated iridium(iii) photosensitizer, a bioinspired diiron complex, and TEA in aqueous acetone, proved to be catalytically active for photoinduced H(2) production, with up to 660 turnovers over 8 h of irradiation.