Novel Photoinduced Phase Transition Observed in Three-dimensional Liquid-crystalline Phase of Azobenzene Compound

Novel Photoinduced Phase Transition Observed in Three-dimensional Liquid-crystalline Phase of Azobenzene Compound
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偶氮苯化合物三维液晶相中观察到的新型光致相变

DOI:
10.1246/cl.2007.1108
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发表时间:
2007
期刊:
影响因子:
1.6
通讯作者:
H. Yokoyama
H. Yokoyama
中科院分区:
化学4区
文献类型:
--
作者:
Takahiro Yamamoto;I. Nishiyama;H. Yokoyama

文献摘要

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合成了一种具有两种高度有序液晶相的新型双手性偶氮苯化合物。其中一个中间相被发现,通过结晶性研究,是一个手性诱导的三维(3D)液晶相。我们首次证明了液晶三维结构的光致相变。
A novel dichiral azobenzene compound which shows two kinds of highly ordered liquid-crystalline phases was prepared. One of the mesophases was found, by miscibility studies, to be a chirality-induced three-dimensional (3D) liquid crystal phase. We, for the first time demonstrate the photoinduced phase transition of the liquid-crystalline 3D structure.