Sugar Surfactant Based Microemulsions at Solid Surfaces: Influence of the Oil Type and Surface Polarity.

Sugar Surfactant Based Microemulsions at Solid Surfaces: Influence of the Oil Type and Surface Polarity.
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固体表面基于糖表面活性剂的微乳液:油类型和表面极性的影响

DOI:
10.1021/acs.langmuir.6b03441
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发表时间:
2016
期刊:
Langmuir : the ACS journal of surfaces and colloids
影响因子:
--
通讯作者:
Wellert
Wellert
中科院分区:
--
文献类型:
--
作者:
Vargas-Ruiz;Soltwedel;Micciulla;Feoktystov;von Klitzing;Hellweg;Wellert

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用中子散射技术(SANS、NR和GISANS)研究了糖-表面活性剂双连续微乳液在体相和亲、疏水固体平面上的结构。在不同的油水比下,考察了油的种类(十四烷和油酸甲酯)对表面附近结构性质的影响。对于亲水表面,散射长度密度分布的分析表明,在两组微乳液中,垂直于固-液界面的油域和水域都是诱导有序的。在疏水表面,观察到含有极性油和非极性油的微乳液在近表面有序性上的差异。
The structure of sugar-surfactant-based bicontinuous microemulsions in the bulk and at hydrophilic and hydrophobic solid planar surfaces was studied by means of neutron scattering techniques (SANS, NR, and GISANS). In particular, the influence of the type of oil (tetradecane and methyl oleate) on the structural properties in the vicinity of surfaces was investigated at different oil-to-water ratios. In the case of hydrophilic surfaces, the analysis of the scattering length density profiles reveals an induced ordering of the oil and water domains perpendicular to the solid–liquid interface in both sets of microemulsions. At hydrophobic surfaces, differences in the near-surface ordering between microemulsions containing polar and nonpolar oils are observed.
胶体悬浮液中的残存结构从 3D 挤压到 2D。
DOI: --
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影响因子: 8.6
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