Highly oxygen permselective membrane prepared from cobalt-complexed polyazomethine containing a ligand and a tri- or tetrasiloxane in the main chain
Highly oxygen permselective membrane prepared from cobalt-complexed polyazomethine containing a ligand and a tri- or tetrasiloxane in the main chain
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由主链中含有配体和三硅氧烷或四硅氧烷的钴络合聚甲亚胺制备的高氧选择性渗透膜
DOI：
10.1002/marc.1995.030160809
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发表时间：
1995
影响因子：
4.6
通讯作者：
E. Oikawa
中科院分区：
文献类型：
--
作者：
Kyounghan Shin;T. Aoki;E. Oikawa
合成了两种主链上含有三齿配体和低聚二甲基硅氧烷重复对的聚甲亚胺，并与钴离子形成配合物。所得聚合物复合物膜在1 atm压差下显示出非常好的氧选择渗透性，这非常接近文献中报道的α对Po2数据图中的上边界线。这些配合物被认为具有氧载体的功能。
Two types of polyazomethines containing repetitive pairs of a tridentated ligand and an oligodimethylsiloxane in the backbone were synthesized and complexed with cobalt ion. The resulting polymer complex membranes showed very good oxygen permselectivity at 1 atm pressure difference, which is very close to the upper boundary line in an α vs. Po2 plot of data reported in the literature. The complexes are thought to function as oxygen carrier.