Preparation and the catalytic activity of novel Pd nanocluster catalysts utilizing an oligosilsesquioxane ligand
Preparation and the catalytic activity of novel Pd nanocluster catalysts utilizing an oligosilsesquioxane ligand
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DOI：
10.1007/s10562-006-0165-0
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发表时间：
2006-11
影响因子：
2.8
通讯作者：
K. Wada;K. Yano;T. Kondo;T. Mitsudo
中科院分区：
文献类型：
--
作者：
K. Wada;K. Yano;T. Kondo;T. Mitsudo
乙酸钯与新合成的倍半硅氧烷-吡啶基配体一起对苯甲醇有氧氧化成苯甲醛表现出优异的催化活性。 TEM 测量揭示了反应期间 Pd 纳米团簇的原位形成。
Palladium acetate together with a newly synthesized silsesquioxane-pyridyl ligand showed excellent catalytic activity towards the aerobic oxidation of benzyl alcohol to benzaldehyde. TEM measurements revealed the in situ formation of Pd nanoclusters during the reaction period.