Highly efficient dehalogenation using hydroxyapatite-supported palladium nanocluster catalyst with molecular hydrogen
Highly efficient dehalogenation using hydroxyapatite-supported palladium nanocluster catalyst with molecular hydrogen
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DOI：
10.1039/b408185d
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发表时间：
2004-01-01
期刊：
影响因子：
9.8
通讯作者：
Kaneda, K
中科院分区：
文献类型：
--
作者：
Hara, T;Mori, K;Kaneda, K
羟基磷灰石负载的Pd纳米团簇（PdHAP）能有效地催化各种有机卤化物在大气分子氢存在下的脱卤反应，氯苯在10 h内得到10000的优良TON.此外，还实现了卤代酚在水相条件下的脱卤。
A hydroxyapatite-supported Pd nanocluster (PdHAP) efficiently catalysed the dehalogenation of various organic halides in the presence of atmospheric molecular hydrogen; chlorobenzene gave benzene in an excellent TON of 10000 for 10 h. Moreover, the dehalogenation of halophenols in aqueous conditions was also achieved.