Anionic stitching polymerization of styryl(vinyl)silanes for the synthesis of sila-cyclic olefin polymers
Anionic stitching polymerization of styryl(vinyl)silanes for the synthesis of sila-cyclic olefin polymers
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苯乙烯基（乙烯基）硅烷的阴离子缝合聚合用于合成硅杂环烯烃聚合物
DOI：
10.1039/d2cc00721e
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发表时间：
2022
期刊：
影响因子：
--
通讯作者：
R.
中科院分区：
文献类型：
--
作者：
Ikeda;S.; Shintani;R.
利用苯乙烯基（乙烯基）硅烷的阴离子拼接聚合反应，合成了一种主链具有稠合硅双环结构的新型含硅碳聚合物。所得聚合物被发现是热稳定的，具有相对高的玻璃化转变温度和在可见光区高度透明。
Anionic stitching polymerization of styryl(vinyl)silanes has been developed for the synthesis of a new type of silicon- and carbon-containing polymer possessing fused sila-bicyclic structures in the main chain. The obtained polymers were found to be thermally stable with relatively high glass-transition temperatures and highly transparent in the visible light region.