Acetonitrile-dicarbon-yl(η-penta-methyl-cyclo-penta-dien-yl)iron(II) tetra-fluorido-borate.
Acetonitrile-dicarbon-yl(η-penta-methyl-cyclo-penta-dien-yl)iron(II) tetra-fluorido-borate.
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乙腈二甲苯（ηpenta-甲基-Cyclo-penta-dien-yl）铁（II）TETRA-FLUORIDO-bITER。
DOI：
10.1107/s1600536811021350
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发表时间：
2011-07-01
期刊：
影响因子：
--
通讯作者：
Bala MD
中科院分区：
文献类型：
--
作者：
M'thiruaine CM;Friedrich HB;Changamu EO;Bala MD
在标题化合物[Fe{η5-C5(CH3)5}(NCCH3)(CO)2]BF4的结构中，铁原子周围的配体以伪八面体三足钢琴凳的方式排列，其中五甲基环戊二烯(CP*)配体占据三个顶端配位位置，而两个羰基和一个乙腈配体形成配位基轴。Fe-N键长为1.924 (3) ？，Fe-CP*质心距为1.722 ？
In the structure of the title compound, [Fe{η5-C5(CH3)5}(NCCH3)(CO)2]BF4, the arrangement of ligands around the Fe atom is in a pseudo-octahedral three-legged piano-stool fashion in which the pentamethylcyclopentadienyl (Cp*) ligand occupies three apical coordination sites, while the two carbonyl and one acetonitrile ligands form the basal axes of the coordination. The Fe—N bond length is 1.924 (3) Å and the Fe—Cp* centroid distance is 1.722 Å.