A highly efficient metal-free protocol for the synthesis of linear polydicyclopentadiene

A highly efficient metal-free protocol for the synthesis of linear polydicyclopentadiene
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DOI:
10.1039/d1py00191d
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发表时间:
2021
期刊:
影响因子:
4.6
通讯作者:
Xuejin Yang;Laura M. Murphy;F. Haque;Scott M. Grayson;Andrew J Boydston
Xuejin Yang;Laura M. Murphy;F. Haque;Scott M. Grayson;Andrew J Boydston
中科院分区:
化学2区
文献类型:
--
作者:
Xuejin Yang;Laura M. Murphy;F. Haque;Scott M. Grayson;Andrew J Boydston

文献摘要

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我们开发了一种高效的线性聚双环戊二烯(pDCPD)通过光氧化还原介导的无金属开环易位聚合(MF-ROMP)的合成,并研究了线性pDCPD的Tg-Mn依赖性。
We have developed a highly efficient synthesis of linear polydicyclopentadiene (pDCPD) via photoredox mediated metal-free ring-opening metathesis polymerization (MF-ROMP) and investigated the Tg–Mn dependence of linear pDCPD.