Carbonyl(η 5 -cyclopentadienyl)(isocyanotriphenylborato-κ C )(triphenylphosphine-κ P )iron(II)
Carbonyl(η 5 -cyclopentadienyl)(isocyanotriphenylborato-κ C )(triphenylphosphine-κ P )iron(II)
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羰基(η 5 -环戊二烯基)(异氰基三苯基硼酸-κ C )(三苯基膦-κ P )铁(II)
DOI:
10.1107/s1600536805015369
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发表时间:
2005
影响因子:
0.9
通讯作者:
Mari Owaribe
中科院分区:
文献类型:
--
作者:
H. Nakazawa;Masumi Itazaki;Mari Owaribe
In the title compound, [Fe(C5H5)(C19H15BN)(C18H15P)(CO)], the FeII atom is coordinated by a carbonyl group, a triphenylphosphine ligand, an isocyanotriphenylborate ligand and a cyclopentadienyl ligand in a piano-stool structure. Two crystallographically independent molecules exist in the asymmetric unit; the Fe—CN, C≡N and CN—B bond distances are 1.866 (3), 1.157 (3) and 1.584 (4) A, respectively, for one molecule, and 1.879 (3), 1.157 (3) and 1.587 (4) A, respectively, for the other.