Control of supramolecular rectangle self-assembly with a molecular template
Control of supramolecular rectangle self-assembly with a molecular template
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用分子模板控制超分子矩形自组装
DOI：
10.1021/ja0733282
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发表时间：
2007-08-01
影响因子：
15
通讯作者：
Stang, Peter J.
中科院分区：
文献类型：
--
作者：
Li, Shan-Shan;Yan, Hui-Juan;Stang, Peter J.
介绍了一种控制超分子双环在高取向热解石墨（HOPG）表面自组装的方法。使用1，3，5-三（10-羧基癸氧基）苯（TCDB），它自组装形成一个稳定的单分子层与HOPG上的纳米级空腔，模板的超分子矩形的沉积过程中证明。控制分子分布，实现单分散，因为双环自组织到TCDB模板的空腔中。
A facile method for controlling the self-assembly of supramolecular metallocycles on a highly oriented pyrolytic graphite (HOPG) surface is described. The process was demonstrated using 1,3,5-tris(10-carboxydecyloxy)benzene (TCDB), which self-assembles to form a stable monolayer with nanoscale cavities on HOPG, to template the deposition of supramolecular rectangles. Molecular distribution is controlled and monodispersion is achieved as the metallocycles self-organize into the cavities of the TCDB template.