A modular synthesis approach to multinuclear heterometallic oxo clusters in polyoxometalates

A modular synthesis approach to multinuclear heterometallic oxo clusters in polyoxometalates
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DOI:
10.1039/c7cc04072e
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发表时间:
2017-07-11
影响因子:
4.9
通讯作者:
Mizuno, Noritaka
Mizuno, Noritaka
中科院分区:
化学2区
文献类型:
--
作者:
Minato, Takuo;Suzuki, Kosuke;Mizuno, Noritaka

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我们报道了一种“模块化合成方法”来合成多核杂金属氧簇。这种方法允许的POM的合成含有nonanuclear {CrMn 4} Lu 2Ag 2簇与最广泛的各种金属之间的离散的金属氧簇制备日期。
We report a "modular synthesis approach'' to multinuclear heterometallic oxo clusters in lacunary polyoxometalates (POMs). This approach allowed the synthesis of a POM containing a nonanuclear {CrMn4}Lu2Ag2 cluster with the widest variety of metals among the discrete metal oxo clusters prepared to date.