A 2D solid-state NMR experiment to resolve overlapping aromatic resonances of thiophene-based nematogens.
A 2D solid-state NMR experiment to resolve overlapping aromatic resonances of thiophene-based nematogens.
复制标题
二维固态核磁共振实验，用于解决基于噻吩的线虫的重叠芳香族共振。
DOI：
10.1021/ja051160j
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发表时间：
2005
影响因子：
15
通讯作者：
Ramamoorthy,Ayyalusamy
中科院分区：
文献类型：
--
作者：
Narasimhaswamy,Tanneru;Lee,Dong-Kuk;Yamamoto,Kazutoshi;Somanathan,Narayanasastri;Ramamoorthy,Ayyalusamy
In this study, we demonstrate the feasibility of resolving overlapping13C chemical shift spectral lines of aromatic rings in a thiophene-based nematogen in the mesophase using a 2D PITANSEMA solid-state NMR method. This technique provided the information about chemical shift values as well as dipolar couplings that are used for determining the orientational order parameter. Large C−H dipolar coupling values measured for thiophene in contrast to phenyl rings suggest that the heterocyclic ring is not part of the molecular axis. Using the order parameter, we determined the orientation of C−H vectors of the thiophene ring. We believe that the 2D solid-state NMR can be extended to other types of liquid crystalline materials such as the banana-based mesogens for determining the orientational order and bent angle.
