Bulk heterojunction organic solar cells utilizing 1,4,8,11,15,18,22,25-octahexylphthalocyanine
Bulk heterojunction organic solar cells utilizing 1,4,8,11,15,18,22,25-octahexylphthalocyanine
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DOI：
10.1016/j.solmat.2011.06.039
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发表时间：
2011-11
影响因子：
6.9
通讯作者：
Tetsuro Hori;Naoki Fukuoka;T. Masuda;Miyake Yasuo;H. Yoshida;A. Fujii;Y. Shimizu;M. Ozaki
中科院分区：
文献类型：
--
作者：
Tetsuro Hori;Naoki Fukuoka;T. Masuda;Miyake Yasuo;H. Yoshida;A. Fujii;Y. Shimizu;M. Ozaki
研究了可溶性酞菁衍生物1，4，8，11，15，18，22，25-八己基酞菁（C6 PcH 2）的异质结太阳能电池。通过旋涂C6 PcH 2和1-（3-甲氧羰基）-丙基-1-1-苯基-（6，6）C61（PCBM）的混合溶液制备活性层。C6 PcH 2和PCBM体异质结太阳能电池的光伏特性显示出强烈的活性层厚度依赖性，并明确了最佳活性层厚度为120 nm。通过在正极和活性层之间插入MoO 3空穴传输缓冲层，FF和能量转换效率分别提高了0.50和3.2%。利用C6 PcH 2和聚3-己基噻吩作为活性层材料，LiF/Al/MoO 3结构作为中间层，研究了叠层有机薄膜太阳能电池，获得了1.27V的高电压。
Bulk heterojunction solar cells utilizing soluble phthalocyanine derivative, 1,4,8,11,15,18,22,25-octahexylphthalocyanine (C6PcH2) have been investigated. The active layer was fabricated by spin-coating the mixed solution of C6PcH2and 1-(3-methoxy-carbonyl)-propyl-1-1-phenyl-(6,6)C61 (PCBM). The photovoltaic properties of the solar cell with bulk heterojunction of C6PcH2and PCBM demonstrated the strong dependence of active layer thickness, and the optimized active layer thickness was clarified to be 120nm. By inserting MoO3hole transport buffer layer between the positive electrode and active layer, the FF and energy conversion efficiency were improved to be 0.50 and 3.2%, respectively. The tandem organic thin-film solar cell has also been studied by utilizing active layer materials of C6PcH2and poly(3-hexylthiophene) and the interlayer of LiF/Al/MoO3structure, and a high Vocof 1.27V has been achieved.