Synthesis and Characterization of C 10 H 10 -Bridged Bimetallic Ruthenium Complexes
Synthesis and Characterization of C 10 H 10 -Bridged Bimetallic Ruthenium Complexes
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DOI：
10.1021/om0493659
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发表时间：
2005-01
期刊：
影响因子：
2.8
通讯作者：
S. Liu;Quanyuan Hu;Peng Xue;T. Wen;Ian D. Williams;G. Jia
中科院分区：
文献类型：
--
作者：
S. Liu;Quanyuan Hu;Peng Xue;T. Wen;Ian D. Williams;G. Jia
用(3E，5E，7E)-HC⋮与RuHCl(CO)(PPh_3)_3反应生成[RuCl(CO)(PPh_3)_2]_2(μ-CHCHCHCHCHCHCHCH)。后者与PMe3反应生成[RuCl(CO)(PMe3)3]2(μ-CHCHCHCHCHCHCHCHCHCHCHCH)，其结构经X-射线衍射法确证。研究了后者的C10H10桥联配合物的电化学性质。
Treatment of RuHCl(CO)(PPh3)3 with (3E,5E,7E)-HC⋮CCHCHCHCHCHCHC⋮CH produces [RuCl(CO)(PPh3)2]2(μ-CHCHCHCHCHCHCHCHCHCH). The latter complex reacts with PMe3 to give [RuCl(CO)(PMe3)3]2(μ-CHCHCHCHCHCHCHCHCHCH), the structure of which has been confirmed by X-ray diffraction. The electrochemical properties of the latter C10H10-bridged complex have been investigated.