Nickel-catalyzed regio- and stereoselective silylation of terminal alkenes with silacyclobutanes: Facile access to vinylsilanes from alkenes
Nickel-catalyzed regio- and stereoselective silylation of terminal alkenes with silacyclobutanes: Facile access to vinylsilanes from alkenes
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DOI：
10.1021/ja070938t
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发表时间：
2007-05-16
影响因子：
15
通讯作者：
Oshima, Koichiro
中科院分区：
文献类型：
--
作者：
Hirano, Koji;Yorimitsu, Hideki;Oshima, Koichiro
在镍催化下用硅杂环丁烷处理末端烯烃导致烯烃的甲硅烷基化，并以高度区域选择性和立体选择性的方式产生相应的乙烯基硅烷。该反应提供了从普通末端烯烃以及苯乙烯、1，3-二烯和丙烯酸酯开始的乙烯基硅烷的容易的途径。
Treatment of terminal alkenes with silacyclobutanes under nickel catalysis resulted in silylation of the alkenes and yielded the corresponding vinylsilanes in a highly regio- and stereoselective fashion. The reaction provides a facile access to vinylsilanes starting from trivial terminal alkenes as well as styrenes, 1,3-dienes, and acrylate esters.