O2 chemistry of dicopper complexes with alkyltriamine ligands. Comparing synergistic effects on O2 binding.
O2 chemistry of dicopper complexes with alkyltriamine ligands. Comparing synergistic effects on O2 binding.
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二铜与烷基三胺配体配合物的 O2 化学。
DOI：
10.1021/ic0602446
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发表时间：
2006
影响因子：
4.6
通讯作者：
Costas,Miquel
中科院分区：
文献类型：
--
作者：
Company,Anna;Lamata,Diana;Poater,Albert;Solà,Miquel;Rybak-Akimova,ElenaV;QueJr,Lawrence;Fontrodona,Xavier;Parella,Teodor;Llobet,Antoni;Costas,Miquel
合成了两种含叔N-甲基化六氮杂配体的双铜（I）配合物，并将其与单核体系进行了比较，结果表明，金属中心之间的协同作用对O2的活化具有重要意义.
Two dicopper(I) complexes containing tertiary N-methylated hexaaza ligands which impose different steric constraints to the Cu ions have been synthesized, and their reactivity toward O2has been compared with a mononuclear related system, highlighting the importance of cooperative effects between the metal centers in O2activation.