Molecular geometry directed Kagome and honeycomb networks: Toward two-dimensional crystal engineering
Molecular geometry directed Kagome and honeycomb networks: Toward two-dimensional crystal engineering
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DOI：
10.1021/ja0583362
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发表时间：
2006-03-22
影响因子：
15
通讯作者：
De Feyter, S
中科院分区：
文献类型：
--
作者：
Furukawa, S;Uji-i, H;De Feyter, S
在这里，我们提出了一个二维（2D）晶体表面上的分子Kagomé网络的形成。该系统提供了一个清晰的例子，说明如何通过设计在2D晶格水平上表达分子几何形状，从而形成开放网络。控制分子网络形成的关键因素是核心对称性，相互作用和连接取代基的位置和取向，以及网络和表面之间的对称匹配。
We present here the formation of a molecular Kagomé network within a two-dimensional (2D) crystal on a surface. This system provides a clear example of how, by design, molecular geometry can be expressed at the level of the 2D crystal lattice, leading to the formation of open networks. Key elements to control molecular network formation are core symmetry, location and orientation of interacting and connecting substituents, as well as symmetry matching between the networks and the surface.