Microwave-Assisted Solvothermal Synthesis of a Dynamic Porous Metal-Carboxylate Framework
Microwave-Assisted Solvothermal Synthesis of a Dynamic Porous Metal-Carboxylate Framework
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微波辅助溶剂热合成动态多孔金属羧酸盐骨架
DOI：
10.1021/cg800623v
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发表时间：
2008-11
影响因子：
3.8
通讯作者：
Chen, Xiao-Ming
中科院分区：
文献类型：
--
作者：
Zhang, Yue-Biao;Wang, Xiao-Feng;Huang, Hong;Zhang, Jie-Peng;Chen, Xiao-Ming
以Cu（NO3）2·3 H2O和V型配体4，4-二羟基二苯甲酸（H2oba）为配体，合成了动态金属羧酸盐骨架[Cu 2（oba）2（DMF）2]·5.25DMF（MCF-23），该骨架具有基于桨轮二次谐波的菱形网格的波状层状结构。
By treating Cu(NO3)2·3H2O with a V-shaped ligand 4,4ʼ-oxydibenzoic acid (H2oba), a dynamic metal-carboxylate framework [Cu2(oba)2(DMF)2]·5.25DMF (MCF-23) was synthesized, which features a wavelike layer with rhombic grids based on the paddle-wheel seconda