Chirality change of chloronitrobenzene on Au(111) induced by inelastic electron tunneling.

Chirality change of chloronitrobenzene on Au(111) induced by inelastic electron tunneling.
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DOI：
10.1002/anie.200805551
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发表时间：
2009-05
期刊：
Angewandte Chemie
影响因子：
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通讯作者：
V. Simic-Milosevic;Jörg Meyer;K. Morgenstern
V. Simic-Milosevic;Jörg Meyer;K. Morgenstern
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文献类型：
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作者：
V. Simic-Milosevic;Jörg Meyer;K. Morgenstern

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手性变色龙：非弹性电子隧道操纵可用于将随机吸附在 Au(111) 上的单个氯硝基苯 (ClNB) 分子改变为其所需的对映体形式（r 或 l，参见 STM 图像和球棒表示）并改变其旋转方向。手性变化 (260 mV) 和旋转 (380 mV) 的不同阈值电压允许单独引发这些过程。
Chirality chameleon: Inelastic electron tunneling manipulation can be used to change a single chloronitrobenzene (ClNB) molecule, randomly adsorbed on Au(111), into its desired enantiomeric form (r or l, see STM images and ball-and-stick representation) and to vary its rotational orientation. The different threshold voltages for chirality change (260 mV) and rotation (380 mV) allow these processes to be induced separately.