Regioselective C-H Borylation of Heteroaromatic Aldimines with Iridium Complexes
Regioselective C-H Borylation of Heteroaromatic Aldimines with Iridium Complexes
复制标题
铱配合物对杂芳醛亚胺的区域选择性 C-H 硼化
作者：
Sasaki;I.; Ikeda;T.; Amou;T.; Taguchi;J.; Ito;H.; Ishiyama;T.
研究了铱催化的五氟苯胺衍生的杂芳醛亚胺的区域选择性C-H硼化反应。在双（环辛二烯基）（甲氧基）铱{[Ir（OMe）（cod）]2}和1，10-菲咯啉原位形成的铱配合物存在下，各种杂芳醛亚胺被双（频哪醇）二硼进行硼化反应，以良好的产率得到相应的硼化产物。
An iridium-catalyzed regioselective C–H borylation of pentafluoroaniline-derived heteroaromatic aldimines has been developed. Various heteroaromatic aldimines underwent borylation by bis(pinacolato)diboron to afford the corresponding borylated products in good yields in the presence of an iridium complex formed in situ from bis(cyclooctadienyl)(methoxy)iridium {[Ir(OMe)(cod)]2} and 1,10-phenanthroline.