Topological modulation of the porous structure of a coordination polymer constructed from a flexible building block via framework-guest interaction during self-assembly
Topological modulation of the porous structure of a coordination polymer constructed from a flexible building block via framework-guest interaction during self-assembly
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DOI：
10.1039/c5ce01804h
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发表时间：
2016-01-01
期刊：
影响因子：
3.1
通讯作者：
Iki, Nobuhiko
中科院分区：
文献类型：
--
作者：
Masuya-Suzuki, Atsuko;Matsubara, Nozomi;Iki, Nobuhiko
由 Sm(III) 离子和构象灵活的配体构建的配位聚合物的多孔结构由客体溶剂分子调节。含有客体DMF分子的配位聚合物具有隔离的疏水性和亲水性空隙，而含有客体甲醇分子的配位聚合物则具有疏水-亲水表面交替排列的微通道。
The porous structure of a coordination polymer constructed from a Sm(III) ion and a conformationally flexible ligand is modulated by guest solvent molecules. The coordination polymer containing the guest DMF molecule possesses isolated hydrophobic and hydrophilic voids, while the one containing the guest methanol molecule has a microchannel with alternately arranged hydrophobic-hydrophilic surfaces.