A spin-canted Ni(II)4-based metal-organic framework with gas sorption properties and high adsorptive selectivity for light hydrocarbons.
A spin-canted Ni(II)4-based metal-organic framework with gas sorption properties and high adsorptive selectivity for light hydrocarbons.
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DOI：
10.1039/c4cc02396j
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发表时间：
2014-07
影响因子：
4.9
通讯作者：
Jia Li;Ying Guo;Hong-Ru Fu;Jian Zhang;Rong-Bin Huang;Lan-Sun Zheng;J. Tao
中科院分区：
文献类型：
--
作者：
Jia Li;Ying Guo;Hong-Ru Fu;Jian Zhang;Rong-Bin Huang;Lan-Sun Zheng;J. Tao
硝酸镍(II)与异烟酸和2,6-二甲基吡啶-3,5-二甲酸的反应提供了一种新型四核镍(II)基金属有机骨架，该骨架表现出倾斜角为1.65°的自旋倾斜反铁磁性和对轻质烃的高吸附选择性。
The reaction of nickel(II) nitrate with isonicotinic acid and 2,6-dimethyl-pyridine-3,5-dicarboxylic acid affords a novel, tetranuclear nickel(II)-based metal-organic framework that exhibits spin-canted antiferromagnetism with a canted angle of 1.65° and high adsorptive selectivity for light hydrocarbons.