Manganese Oxide(Mn2O3) as Adsorbent for Cadmium.

Manganese Oxide(Mn2O3) as Adsorbent for Cadmium.
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氧化锰(Mn2O3)作为镉的吸附剂。

DOI:
10.2965/jswe.23.116
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发表时间:
2000
期刊:
Journal of Japan Society on Water Environment
影响因子:
--
通讯作者:
Atsushi Uchida
Atsushi Uchida
中科院分区:
--
文献类型:
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作者:
H. Koyanaka;S. Koyanaka;Ruilu Liang;Atsushi Uchida

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研究了Mn_2O_3对水溶液中镉的吸附。研究结果表明:(1)在温度为300 °C,溶液pH=7,镉浓度为1 × 100 mg· l-1的条件下,Mn_2O_3对镉的吸附富集能力为23.2 × 46.6mg · g-1。Mn 2 O3的比表面积为50 m2· g-1。(2)加入0.5mol · l-1HNO 3可将镉从Mn_2O_3上洗脱下来,Mn_2O_3对镉的吸附能力基本恢复到原来的水平。(3)本研究尝试用Mn_2O_3(1g)去除日本秋田吉野矿山废水(0.117mg · l ~(-1)Cd)中的Cd。结果表明,处理后的出水在2.5h内镉浓度降至0.001mg · l-1以下。
In the present study, the adsorption of cadmium on Mn2O3 in aqueous solution was investigated. The Mn2O3 was prepared by heating MnCO3 at 300∼800°C for 4.5 hours.The findings of the present study are as follows:(1) The Mn2O3 showed the ability to adsorb and concentrate cadmium from aqueous solution to levels reaching 23.2∼46.6mg · g-1 under the following conditions : heating temperature=300°C, solution pH=7, and cadmium concentration=1∼100mg · l-1. The surface area of the Mn2O3 was 50m2 · g-1.(2) The cadmium was eluted from the Mn2O3 by adding 0.5mol · l-1 HNO3, and the adsorption ability of the Mn2O3 recovered to nearly the previous level.(3) We attempted to remove cadmium from a sample (1l) of mining effluent (0.117mg · l-1 Cd) from the Yoshino mine in Akita prefecture, Japan using Mn2O3 (1g). The results showed that the cadmium concentration of the treated effluent decreased to under 0.001mg · l-1 in 2.5 hours.