Highly enantioselective transfer hydrogenation of α,β-unsaturated ketones
Highly enantioselective transfer hydrogenation of α,β-unsaturated ketones
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DOI：
10.1021/ja065708d
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发表时间：
2006-10-18
影响因子：
15
通讯作者：
List, Benjamin
中科院分区：
文献类型：
--
作者：
Martin, Nolwenn J. A.;List, Benjamin
我们描述了一种高效的和高对映选择性的α，β-不饱和酮的共轭转移氢化反应，该反应是由叔丁基缬氨酸盐和最近引入的强手性磷酸催化剂（TRIP）催化的。
We describe an efficient and highly enantioselective conjugate transfer hydrogenation of α,β-unsaturated ketones that is catalyzed by a salt made fromtert-butyl valinate and a recently introduced powerful chiral phosphoric acid catalyst (TRIP).