The Reaction Involving One Electron Transfer in Key Step. NO2-Catalyzed Halogenation of Polycyclic Aromatic Compounds with Metal Halides
The Reaction Involving One Electron Transfer in Key Step. NO2-Catalyzed Halogenation of Polycyclic Aromatic Compounds with Metal Halides
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关键步骤涉及一个电子转移的反应。
DOI：
10.1246/bcsj.55.1504
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发表时间：
1982
影响因子：
4
通讯作者：
T. Sugiyama
中科院分区：
文献类型：
--
作者：
T. Sugiyama
在二氧化氮和氧的催化量共存的条件下，卤化铝、卤化钛（IV）和其他一些金属卤化物被发现是多环芳香族化合物的高选择性和区域特异性卤化剂，包括蒽、芘、苯[a]蒽、蒽、菲、萘、三苯、氟蒽、苯并[b]噻吩和二苯并噻吩。
In the co-existence of catalytic amount of nitrogen dioxide and oxygen, aluminum halide, titanium(IV) halide, and some other metal halides have been found to be highly selective and regiospecific halogenating agents for polycyclic aromatic compounds, including anthracene, pyrene, benz[a]anthracene, chrysene, phenanthrene, naphthalene, triphenylene, fluoranthene, benzo[b]thiophene, and dibenzothiophene.