Giant Pores in a Chromium 2,6-Naphthalenedicarboxylate Open-Framework Structure with MIL-101 Topology
Giant Pores in a Chromium 2,6-Naphthalenedicarboxylate Open-Framework Structure with MIL-101 Topology
复制标题
DOI：
10.1002/anie.200805980
复制
发表时间：
2009-01-01
影响因子：
16.6
通讯作者：
Stock, Norbert
中科院分区：
文献类型：
--
作者：
Sonnauer, Andreas;Hoffmann, Frank;Stock, Norbert
在MIL-101结构中用2，6-萘二甲酸酯取代1，4-苯二甲酸酯导致含有直径为39和46 μ m的笼的等网格介孔框架。 采用高通量方法来确定适当的反应条件。该微晶化合物通过分子模拟技术、粉末X射线衍射、N2吸附和TEM研究进行表征。
Large, larger, …︁Replacement of 1,4‐benzenedicarboxylate by 2,6‐naphthalenedicarboxylate in the MIL‐101 structure leads to an isoreticular mesoporous framework containing cages with diameters of 39 and 46 Å. High‐throughput methods are employed to determine appropriate reaction conditions. The microcrystalline compound is characterized by molecular simulation techniques, powder X‐ray diffraction, N2‐sorption, and TEM investigations.