From ferromagnets to high-spin molecules: the role of the organic ligands
From ferromagnets to high-spin molecules: the role of the organic ligands
复制标题
从铁磁体到高自旋分子：有机配体的作用
DOI：
--
复制
发表时间：
1999
期刊：
影响因子：
--
通讯作者：
E. Rivière
中科院分区：
文献类型：
--
作者：
T. Mallah;Arnaud Marvilliers;E. Rivière
有机配体的性质是影响双金属氰化物桥接体系维数的关键因素。通过控制金属离子周围配位位点的数量，可以获得具有新结构和原有结构的体系。阻断NiII和MnII周围的四个配位位点，可以根据剩余两个可用位点的位置获得具有新结构的新结构：在反式或顺式位置。
The nature of the organic ligands is crucial in influencing the dimensionality of bi–metallic cyanide–bridged systems. By controlling the number of coordination sites around a metal ion, we show that systems with new structure and original architecture may be obtained. Blocking four of the coordination sites around NiII and MnII, new structures with new architectures can be obtained depending on the position of the remaining two available sites: in the trans or cis position.