Metal clusters as ligands: substitution of Fe ions in Fe/Mo/S clusters by thiophilic Cu(I) ions to give clusters with [Cu4Mo2Fe2S8]4+ and [Cu5Mo3Fe4S11]6+ cores.
Metal clusters as ligands: substitution of Fe ions in Fe/Mo/S clusters by thiophilic Cu(I) ions to give clusters with [Cu4Mo2Fe2S8]4+ and [Cu5Mo3Fe4S11]6+ cores.
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DOI：
10.1002/anie.200462596
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发表时间：
2005-03
影响因子：
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通讯作者：
M. Koutmos;D. Coucouvanis
中科院分区：
文献类型：
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作者：
M. Koutmos;D. Coucouvanis
Rational synthesis of high nuclearity Mo/Fe/S clusters: the reductive coupling approach in the convenient synthesis of (Cl (4)-cat)(2) Mo (2) Fe (6) S (8)(PR (3))(6)[R= Et,(n) Pr,(n) Bu] and the new [(Cl (4)-cat)(2) Mo (2) Fe (2) S (3) O (PEt (3))(3) Cl]-1/2 (Fe (PEt (3))(2)(MeCN)(4)) and (Cl (4)-cat)(2) Mo (2) Fe (3) S (5)(PEt (3))(5) clusters.
