Ni-catalyzed two-component reductive dicarbofunctionalization of alkenes via radical cyclization
Ni-catalyzed two-component reductive dicarbofunctionalization of alkenes via radical cyclization
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DOI：
10.1039/c8cc00358k
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发表时间：
2018-03-11
影响因子：
4.9
通讯作者：
Diao, Tianning
中科院分区：
文献类型：
--
作者：
Kuang, Yulong;Wang, Xuefeng;Diao, Tianning
发展了一种烯烃的还原性双碳官能化反应，并将其应用于取代碳环和取代杂环的制备。该反应条件避免了使用对空气敏感的有机金属试剂，并且与宽范围的溴亲电试剂和宽范围的取代基相容，以优异的产率得到环状产物。
A reductive dicarbofunctionalization reaction of alkenes has been developed and applied to the preparation of substituted carbo- and heterocycles. The reaction conditions avoid the use of air-sensitive organometallic reagents, and are compatible with a broad range of bromo-electrophiles and a wide variety of substituents to give cyclic products in excellent yields.