Superelectrophilic Amidine Dications: Dealkylation by Triflate Anion
Superelectrophilic Amidine Dications: Dealkylation by Triflate Anion
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超亲电脒二阳离子：三氟甲磺酸根阴离子脱烷基化
DOI：
10.1002/anie.201202990
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发表时间：
2012
期刊：
影响因子：
--
通讯作者：
Kovacevic L
中科院分区：
文献类型：
--
作者：
Kovacevic L
Superelectrophiles: Formamides were designed that when treated with triflic anhydride would be transformed into superelectrophilic amidine dications. These dications were so electrophilic that they underwent in situ dealkylation by the triflate anion (see scheme; Tf= trifluoromethanesulfonyl). DFT calculations were used to determine the mechanistic details of the dealkylation reaction.
