The Chemical Properties of Dioxygen Difluoride
The Chemical Properties of Dioxygen Difluoride
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DOI：
10.1021/ja00893a004
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发表时间：
1963-05
影响因子：
15
通讯作者：
A. G. Streng
中科院分区：
文献类型：
--
作者：
A. G. Streng
即使在非常低的温度下，二氟化氧也具有非常高的氧化能力。研究了O2F2与Cl2、Br2、I2、P、S及其低氟化物的反应性，以及与氮氟化物、HC1、HBr、H»S等化合物的反应性。在与GIF、BrF3、SF4、HC1和HBr的反应中观察到中间加成产物的形成。大多数中间体只存在一段时间。
Dioxygen difluoride has a remarkably high oxidizing power, even at very low temperatures. The reactivity of O2F2 with Cl2, Br2, I2, P, S, and their lower fluorides, as well as with the fluorides of nitrogen, with HC1, HBr, H» S and with some other compounds was studied. Formation of intermediate addition products was observed in the reactions with GIF, BrF3, SF4, HC1 and HBr. Most intermediates have only a transitory existence.