Synthesis and molecular structure of [{Pd2(CH2C6H4P(o-tolyl)2-κC,P)2(µ3-3,5-dmpz-N,N′,C4)2Ag(µ-ClO4)}2] (3,5-dmpz = 3,5-dimethylpyrazolato), a silver derivative showing unprecedented η1-azolato coordination
Synthesis and molecular structure of [{Pd2(CH2C6H4P(o-tolyl)2-κC,P)2(µ3-3,5-dmpz-N,N′,C4)2Ag(µ-ClO4)}2] (3,5-dmpz = 3,5-dimethylpyrazolato), a silver derivative showing unprecedented η1-azolato coordination
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DOI：
10.1039/a805938a
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发表时间：
1998
影响因子：
4.9
通讯作者：
L. Falvello;J. Forniés;Antonio Martín;R. Navarro;V. Sicilia;P. Villarroya
中科院分区：
文献类型：
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作者：
L. Falvello;J. Forniés;Antonio Martín;R. Navarro;V. Sicilia;P. Villarroya
The reaction of [Pd2(CH2C6H4P(o-tolyl)2-κC,P)2(µ-3,5-dmpz)2] (1) with AgClO4 renders [{Pd2(CH2C6H4P(o-tolyl)2-κC,P)2(µ3-3,5-dmpz-N,N′,C4)2Ag(η2-µ-ClO4)}2] (2), a palladium–silver derivative displaying an unprecedented dmpz bridging ligand η1 bonded to the Ag centers, involving only the C4 atom of each dmpz ligand.
