Detection of Unpredictable Molecular Recognition through Carbonyl-π Interaction in Poly(methyl acrylate)-Silica Hybrids1
Detection of Unpredictable Molecular Recognition through Carbonyl-π Interaction in Poly(methyl acrylate)-Silica Hybrids1
复制标题
通过聚（丙烯酸甲酯）-二氧化硅杂化物中的羰基-π 相互作用检测不可预测的分子识别1
DOI：
10.1295/polymj.30.394
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发表时间：
1998
期刊：
影响因子：
2.8
通讯作者：
C. Hirayama
中科院分区：
文献类型：
--
作者：
H. Ihara;S. Uemura;S. Okazaki;C. Hirayama
通过接枝到硅胶上，发现无规聚丙烯酸甲酯对含π电子的多环化合物表现出难以预测的特异性保留选择性，仿佛进行了分子形状识别。这种特异性与其他几种聚合物接枝硅胶的保留行为进行了讨论，并提出了一个参数f来评估π-π相互作用的贡献。
It was detected through grafting onto silica that atactic poly(methyl acrylate) showed unpredictably specific retention selectivity against polycyclic compounds with π-electrons as if molecular-shape recognition was performed. This specificity was discussed with retention behaviors in several other polymer-grafted silicas and by proposing a parameter f to evaluate the contribution of π-π interaction.