Alkali-earth metal lead(ii) oxyhalide Ba27Pb8O8Cl54 exhibiting interesting [Pb4Ba4O4](8+) species
Alkali-earth metal lead(ii) oxyhalide Ba27Pb8O8Cl54 exhibiting interesting [Pb4Ba4O4](8+) species
复制标题
碱土金属卤氧化铅 Ba27Pb8O8Cl54 表现出有趣的 [Pb4Ba4O4](8 ) 物种
DOI：
10.1039/c9nj05419g
复制
发表时间：
2020
影响因子：
3.3
通讯作者：
Wu Yicheng
中科院分区：
文献类型：
--
作者：
Li Zhuang;Jiang Xingxing;Xing Wenhao;Lin Zheshuai;Yao Jiyong;Wu Yicheng
The discovery of compounds with novel topologies is likely to extend structural diversity and trigger intriguing physical properties. Herein, the interesting [Pb4Ba4O4]8+ species has been discovered in alkali-earth metal lead(II) oxyhalide Ba27Pb8O8Cl54. Besides, the crystal structures, infrared/Raman spectroscopy, UV-Vis-NIR diffuse reflectance spectroscopy and electronic band structures of Ba27Pb8O8Cl54 have been studied.
