Use of adsorption isotherms of light normal alkanes for characterizing microporous activated carbons

Use of adsorption isotherms of light normal alkanes for characterizing microporous activated carbons
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利用轻质正构烷烃的吸附等温线表征微孔活性炭

DOI:
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发表时间:
1991
期刊:
影响因子:
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通讯作者:
R. Madey
R. Madey
中科院分区:
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文献类型:
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作者:
X. Lu;M. Jaroniec;R. Madey

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测定了轻质正构烷烃在三种不同的活性碳上的吸附等温线,并与苯在这些炭上的吸附等温线进行了比较。通过Dubinin-Radushkevich方程的分析表明,乙烷、丙烷和正丁烷的吸附等温线可用于描述活性炭微孔结构。在这些研究的基础上,作者建议使用正丁烷作为微孔活性碳表征的参比吸附剂。
Adsorption isotherms of light normal alkanes on three different activated carbons were measured and compared with benzene adsorption isotherms on these carbons. Analysis by means of the Dubinin-Radushkevich equation revealed the utility of the adsorption isotherms of ethane, propane, and n-butane for describing the microporosity of activated carbons. On the basis of these studies, the authors recommend that n-butane be used as a reference adsorbate for characterization of microporous activated carbons.