Comment on "Failure of the work-Hamiltonian connection for free-energy calculations".
Comment on "Failure of the work-Hamiltonian connection for free-energy calculations".
复制标题
对“自由能计算的功哈密尔顿连接失败”发表评论。
DOI：
10.1103/physrevlett.101.098903
复制
发表时间：
2007
影响因子：
8.6
通讯作者：
L. Peliti
中科院分区：
文献类型：
--
作者：
L. Peliti
我指出，维拉尔和鲁比提出的反对自由能计算中功与汉密尔顿联系的论点，如果正确的话，意味着热力学自由能通过配分函数的对数的统计力学表达的失败。
I point out that the arguments raised by Vilar and Rubi against the work-Hamiltonian connection in free-energy calculations imply, if correct, the failure of the statistical mechanical expression of the thermodynamical free-energy via the logarithm of the partition function.