Aggregation of chiral hexanuclear complex-cations into cationic metallosupramolecules with concomitant aggregation of inorganic counter-anions into anionic clusters
Aggregation of chiral hexanuclear complex-cations into cationic metallosupramolecules with concomitant aggregation of inorganic counter-anions into anionic clusters
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DOI：
10.1039/c2ce06539h
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发表时间：
2012-01-01
期刊：
影响因子：
3.1
通讯作者：
Konno, Takumi
中科院分区：
文献类型：
--
作者：
Lee, Raeeun;Igashira-Kamiyama, Asako;Konno, Takumi
以二金(I)金属配体[Au-2(dppe)(D-Hpen)(2)]与Co-III结合制备手性(Au4Co2III)- co -I六核配合物[Au4Co2(dppe)(2)(D-pen)(4)] X-2 （X = Cl-, ClO4-）。在晶体中，发现该配合物的阳离子和反阴离子分别聚集形成大的阳离子金属超分子八面体和惊人的金刚烷类阴离子团簇。
A chiral (Au4Co2III)-Co-I hexanuclear complex, [Au4Co2(dppe)(2)(D-pen)(4)] X-2 (X = Cl-, ClO4-), was prepared from a digold( I) metalloligand, [Au-2(dppe)(D-Hpen)(2)], in combination with Co-III. In the crystal, complex-cations and counter-anions of this complex were found to aggregate separately to form big cationic metallosupramolecular octahedrons and amazing adamantane-like anionic clusters, respectively.