Selective Construction of Pd2Pt and PdPt2 Triangles in a Sandwich Framework: Carbocyclic Ligands as Scaffolds for a Mixed-Metal System
Selective Construction of Pd2Pt and PdPt2 Triangles in a Sandwich Framework: Carbocyclic Ligands as Scaffolds for a Mixed-Metal System
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DOI：
10.1002/chem.201201474
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发表时间：
2012-07-01
影响因子：
4.3
通讯作者：
Ogoshi, Sensuke
中科院分区：
文献类型：
--
作者：
Murahashi, Tetsuro;Usui, Kentaro;Ogoshi, Sensuke
三明治!选择性地合成了Pd (2) Pt和PdPt(2)的混合金属三角-三核夹层配合物。环庚三烯基夹层结构中的Pd (2) Pt和PdPt(2)三角形通过三-三苯基膦配合物的（31）核磁共振分析确定（见图）。
Sandwich time! The mixed-metal triangular-trinuclear sandwich complexes of Pd (2) Pt and PdPt (2) were selectively synthesized. The Pd (2) Pt and PdPt (2) triangles in a cycloheptatrienyl sandwich framework were identified by (31) P NMR analyses of the tris-triphenylphosphine complexes (see scheme).