Synthesis of silicophosphates containing SiO6-octahedra under ambient conditions--reactions of anhydrous H3PO4 with alkoxysilanes.
Synthesis of silicophosphates containing SiO6-octahedra under ambient conditions--reactions of anhydrous H3PO4 with alkoxysilanes.
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环境条件下含SiO6-八面体的硅磷酸盐的合成——无水H3PO4与烷氧基硅烷的反应。
DOI：
10.1039/c2cc31600e
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发表时间：
2012
影响因子：
4.9
通讯作者：
E. Kroke
中科院分区：
文献类型：
--
作者：
Sandra Jähnigen;E. Brendler;U. Böhme;E. Kroke
无水H（3）PO（4）在乙醚溶液中与乙氧基硅烷在室温下反应生成含SiO（6）-单元的硅磷酸盐。单晶X射线结构提供了由交替的SiO（4）-和PO（4）-四面体以及SiO（6）-八面体组成的硅磷酸盐结构的证据。
Anhydrous H(3)PO(4) reacts in diethylether solution at room temperature with ethoxysilanes to form silicophosphates which contain SiO(6)-units. A single crystal X-ray structure provides evidence for silicophosphate structures comprised of alternating SiO(4)- and PO(4)-tetrahedra as well as SiO(6)-octahedra.