Reciprocal regulation between MOFs and polymers
Reciprocal regulation between MOFs and polymers
复制标题
DOI：
10.1016/j.ccr.2022.214601
复制
发表时间：
2022
影响因子：
20.6
通讯作者：
Ami Nishijima;Yuki Kametani;T. Uemura
中科院分区：
文献类型：
--
作者：
Ami Nishijima;Yuki Kametani;T. Uemura
mof -聚合物杂化材料的发展对配位化学和聚合物化学的科学研究都做出了贡献。由金属离子和有机配体组成的mof是一种具有确定尺寸和表面功能的纳米孔的晶体材料。在MOF孔中聚合物的合成、识别和分离方面已经进行了各种各样的研究。聚合物是具有柔性构象的链式分子。聚合物链的独特性质以多种方式影响MOFs，如控制晶体生长、稳定和功能化。本文讨论了MOFs和聚合物在杂化体系中的相互作用。了解它们相互增强的关系为mof -聚合物复合材料的进一步发展提供了新的见解。
The development of MOF–polymer hybrid materials has contributed to both fields of science in coordination chemistry and polymer chemistry. MOFs composed of metal ions and organic ligands are crystalline materials possessing nanopores with defined size and surface functionality. Various efforts have been placed regarding polymer synthesis, recognition, and separation in MOF pores. Polymers are chain molecules with flexible conformations. The unique properties of the polymer chains influences MOFs in multiple ways, such as controlled crystal growth, stabilization, and functionalization. This review discusses the mutual contributions of MOFs and polymers, in hybrid systems. Understanding their reciprocally enhanced relationships provides new insights for further development of MOF-polymer composites.