The Preparation and Photoluminescence Properties of Fluorosilicate Glass Ceramics Containing CeF3:Dy3+ Nanocrystals

The Preparation and Photoluminescence Properties of Fluorosilicate Glass Ceramics Containing CeF3:Dy3+ Nanocrystals
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CeF3:Dy3纳米晶氟硅酸盐微晶玻璃的制备及其光致发光性能

DOI:
10.1088/0256-307x/29/1/017802
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发表时间:
2012
影响因子:
3.5
通讯作者:
Zhang Xiang-Hua
Zhang Xiang-Hua
中科院分区:
物理与天体物理3区
文献类型:
--
作者:
Wu Li-Ang;Fu Heng-Yi;Qian Jiang-Yun;Zhao Da-Liang;Luo Qun;Qiao Xu-Sheng;Fan Xian-Ping;Zhang Xiang-Hua

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Ce3+ and Dy3+ co-doped oxyfluoride glasses and glass ceramics containing CeF3 nanocrystals are prepared in a reducing atmosphere. XRD measurements and the calculated lattice parameters suggest that Dy3+ ions are incorporated with precipitated CeF3 nanocrystals along with a rise in the Dy3+ concentration or an increase in the annealing temperature. The glass ceramics emit white light close to the CIE coordinates of (0.3,0.3), derived from a combination of Ce3+ and Dy3+ emission. The CIE chromaticity coordinates of the Ce3+ and Dy3+ co-doped glass ceramics can be tuned by varying the ratio of Ce3+/Dy3+, while the luminescence intensity can be enhanced by heat treatment above 620°C.
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