New synthesis method for nickel phosphide nanoparticles: solid phase reaction of nickel cations with hypophosphites

New synthesis method for nickel phosphide nanoparticles: solid phase reaction of nickel cations with hypophosphites
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DOI:
10.1039/b903088n
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发表时间:
2009-04
影响因子:
--
通讯作者:
Guojun Shi;Jianyi Shen
Guojun Shi;Jianyi Shen
中科院分区:
--
文献类型:
--
作者:
Guojun Shi;Jianyi Shen

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采用H2PO2−与Ni2+在N2中相对低温固相反应制备了Ni2P纳米粒子,对二苯并噻吩的加氢脱硫和喹啉的加氢脱氮具有较高的活性。
Nanoparticles of Ni2P were simply prepared by a solid phase reaction of H2PO2− with Ni2+ in N2 at relatively low temperatures, which exhibited high activity for the hydrodesulfurization of dibenzothiophene and hydrodenitrogenation of quinoline.