Iodine-Mediated Highly Regio- and Stereoselective Iodoamination of Ferrocenyl Allene: An Approach for the Synthesis of Ferrocene-Containing Allylic Amines
Iodine-Mediated Highly Regio- and Stereoselective Iodoamination of Ferrocenyl Allene: An Approach for the Synthesis of Ferrocene-Containing Allylic Amines
复制标题
碘介导的二茂铁丙二烯的高度区域和立体选择性碘胺化：一种合成含二茂铁烯丙胺的方法
DOI：
10.1021/jo4006206
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发表时间：
2013-05-17
影响因子：
3.6
通讯作者：
Li, Baoguo
中科院分区：
文献类型：
--
作者：
Chen, Shufeng;Yan, Qing;Li, Baoguo
通过二茂铁基丙二烯的碘代胺化反应，发展了一种简单有效的高区域和立体选择性合成含二茂铁烯丙基胺衍生物的方法。该反应的区域选择性和立体选择性可通过大体积二茂铁基团的空间效应来控制。
A straightforward and efficient protocol for the highly regio- and stereoselective synthesis of ferrocene-containing allylic amine derivatives via an iodine-mediated iodoamination of ferrocenyl allene was developed. The regio- and stereoselectivity of this reaction may be controlled by the steric effect of the bulky ferrocene group.