Selective production of hydrogen peroxide and oxidation of hydrogen sulfide in an unbiased solar photoelectrochemical cell
Selective production of hydrogen peroxide and oxidation of hydrogen sulfide in an unbiased solar photoelectrochemical cell
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DOI:
10.1039/c4ee01503g
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发表时间:
2014-09
影响因子:
32.5
通讯作者:
Xu Zong;Hongjun Chen;B. Seger;T. Pedersen;M. Dargusch;E. McFarland;Can Li;Lianzhou Wang
中科院分区:
文献类型:
--
作者:
Xu Zong;Hongjun Chen;B. Seger;T. Pedersen;M. Dargusch;E. McFarland;Can Li;Lianzhou Wang
A solar-to-chemical conversion process is demonstrated using a photoelectrochemical cell without external bias for selective oxidation of hydrogen sulfide (H2S) to produce hydrogen peroxide (H2O2) and sulfur (S). The process integrates two redox couples anthraquinone/anthrahydroquinone and I−/I3−, and conceptually illustrates the remediation of a waste product for producing valuable chemicals.