Organotrifluoroborate Salts as Complexation Reagents for Synthesizing BODIPY Dyes Containing Both Fluoride and an Organo Substituent at the Boron Center
Organotrifluoroborate Salts as Complexation Reagents for Synthesizing BODIPY Dyes Containing Both Fluoride and an Organo Substituent at the Boron Center
复制标题
有机三氟硼酸盐作为络合试剂用于在硼中心合成含有氟化物和有机取代基的 BODIPY 染料
DOI：
10.1021/acs.joc.8b03145
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发表时间：
2019
影响因子：
3.6
通讯作者：
Hao Erhong
中科院分区：
文献类型：
--
作者：
Wang Zhaoyun;Cheng Cheng;Kang Zhengxin;Miao Wei;Liu Qingyun;Wang Hua;Hao Erhong
报道了一种利用原位生成的二吡咯亚甲基与有机三氟硼盐一锅反应制备同时含有F和B中心有机取代基的功能化BODIPY的简便方法。该络合反应利用了稳定且可商业化的有机三氟硼酸钾盐，并提供了一种通过现有合成方法难以获得的各种新型B-官能化BODIPY的途径。
A convenient procedure for the preparation of functionalized BODIPYs bearing both F and an organo substituent at the boron center, using one-pot reactions between in situ formed dipyrromethenes and organotrifluoroborate salts, has been reported. The complexation reaction utilizes stable and commercial accessible organotrifluoroborate potassium salts and provides a facile access to a variety of novel B-functionalized BODIPYs, which are hard to access through current synthetic methods.